Photochemistry and Redox Chemistry of an Unsymmetrical Bimetallic Copper(I) Complex
نویسندگان
چکیده
منابع مشابه
Shining light on dinitrogen cleavage: structural features, redox chemistry, and photochemistry of the key intermediate bridging dinitrogen complex.
The key intermediate in dinitrogen cleavage by Mo(N[t-Bu]Ar)3, 1 (Ar = 3,5-C6H3Me2), has been characterized by a pair of single crystal X-ray structures. For the first time, the X-ray crystal structure of (mu-N2)[Mo(N[t-Bu]Ar)3]2, 2, and the product of homolytic fragmentation of the NN bond, NMo(N[t-Bu]Ar)3, are reported. The structural features of 2 are compared with previously reported EXAFS ...
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ژورنال
عنوان ژورنال: Inorganic Chemistry
سال: 2016
ISSN: 0020-1669,1520-510X
DOI: 10.1021/acs.inorgchem.6b01400